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101.
Gunasekaran Balamurugan Sundarraman Balaji Rengan Ramesh Nattamai S.P. Bhuvanesh 《应用有机金属化学》2019,33(1)
A panel of six new arene Ru (II)‐NHC complexes 2a‐f , (NHC = 1,3‐diethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1a , 1,3‐dicyclohexylmethyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1b and 1,3‐dibenzyl‐(5,6‐dimethyl)benzimidazolin‐2‐ylidene 1c ) were synthesized from the transmetallation reaction of Ag‐NHC with [(η6‐arene)RuCl2]2 and characterized. The ruthenium (II)‐NHC complexes 2a‐f were developed as effective catalysts for α‐alkylation of ketones and synthesis of bioactive quinoline using primary/amino alcohols as coupling partners respectively. The reactions were performed with 0.5 mol% catalyst load in 8 h under aerobic condition and the maximum yield was up to 96%. Besides, the different alkyl wingtips on NHC and arene moieties were studied to differentiate the catalytic robustness of the complexes in the transformations. 相似文献
102.
Johisner Penagos‐Llanos Olimpo García‐Beltrn J. A. Caldern Edgar Nagles J. J. Hurtado 《Electroanalysis》2019,31(4):695-703
The detection of Allura red (AR) by electrochemical reduction using a different electrode from the conventional mercury electrode is presented. A carbon paste with cobalt (II, III) oxide composite electrode (CoOx/CPE) is reported for the first time for the detection of AR. Moreover, others dyes such as tartrazine (TZ), sunset yellow (SY), amaranth (AM), Ponceaut 4‐R (P‐4R), and Sudan (SD) as well as pharmaceutical agents such as paracetamol (PMC) that are present in samples that contained AR did not show a reduced signal between 0.0 and ?0.3 V, which is the potential range where AR reduction was observed. The surface electroactivity was studied using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and scanning electron microscopy (SEM). The presence of CoOX increased the cathodic peak current for AR by more than 50 % and 65 % via CV and square wave voltammetry (SWV), respectively, compared with an unmodified carbon paste electrode. Under the optimal parameters, (pH=3.0, accumulation time (tACC)=60 s and accumulation potential (EACC)=0.50 V), the detection limit for AR was 0.05 μmol L?1. The new sensor was sensitive and stable for the detection of AR. Moreover, it was easily manufactured and very convenient for food samples such as soft and isotonic drinks as well as chili sauce. 相似文献
103.
Yongsheng Song 《Stochastic Processes and their Applications》2019,129(6):2066-2085
As is known, if is a -Brownian motion, a process of form , , is a non-increasing -martingale. In this paper, we shall show that a non-increasing -martingale cannot be form of or , , which implies that the decomposition for generalized -Itô processes is unique: For arbitrary , and non-increasing -martingales , if then we have , and. As an application, we give a characterization to the -Sobolev spaces introduced in Peng and Song (2015). 相似文献
104.
105.
106.
A simple, sensitive and rapid ultra‐high‐performance liquid chromatography–electrospray ionization–tandem mass spectrometry method was developed and validated for the quantification of warfarin and 7‐hydroxy warfarin in Sprague Dawley (SD) rats. Animals were administered a single dose of warfarin sodium formulations (crystalline and amorphous) at 12 mg/kg via oral gavage and blood was drawn over a 96‐h time course. Sample process recoveries, matrix effect and analyte stability were determined. The linearity for warfarin and 7‐hydroxy warfarin was from 5 to 2000 ng/mL in blank SD rat plasma. Correlation coefficients (r2) for standard calibration curves were >.98 and analytes quantified within ±15% of target at all calibrator concentrations. The average percent accuracy and precision for intra‐ and inter‐day were 93.7%–113.8% and ≤12.1%, respectively, for warfarin and 7‐hydroxy warfarin, across the quality control standards (5, 10, 500, 1800 and 2000 ng/mL). Acceptable analytical recovery (>55%) was achieved with process efficiencies >41.5% and matrix effects <139.9% over the analytical range. Both analytes were stable in stock solution, autosampler, benchtop and three cycles of freeze–thaw with percent accuracy ≥90.2% and precision (percent relative standard deviation) ≤14%. The validated method was successfully applied to a pre‐clinical bioavailability study of crystalline and amorphous warfarin sodium formulations in SD rats. 相似文献
107.
For a general dyadic grid, we give a Calderón–Zygmund type decomposition, which is the principle fact about the multilinear maximal function on the upper half‐spaces. Using the decomposition, we study the boundedness of . We obtain a natural extension to the multilinear setting of Muckenhoupt's weak‐type characterization. We also partially obtain characterizations of Muckenhoupt's strong‐type inequalities with one weight. Assuming the reverse Hölder's condition, we get a multilinear analogue of Sawyer's two weight theorem. Moreover, we also get Hytönen–Pérez type weighted estimates. 相似文献
108.
Güllü Canan Hazar Güle 《Mathematical Methods in the Applied Sciences》2019,42(16):5398-5402
By , we denote the set of all sequences such that Σ?nan is summable V whenever Σan is summable U, where U and V are two summability methods. Recently, Sar?göl has characterized the set for k > 1,α > ?1 and arbitrary positive sequences Now, in the present paper, we characterize the sets , k > 1 and , k ≥ 1 for arbitrary positive sequences Hence we extend these results to the range α≥ ? 1. In this way, some open problems in this topic are also completed. 相似文献
109.
Jinghua YANG 《数学年刊B辑(英文版)》2019,40(2):227-236
In this paper, the author gives the discrete criteria and J\o
rgensen inequalities of subgroups for the special linear group on
$\overline{\mathrm{F}}((t))$ in two and higher dimensions. 相似文献
110.